Evaluation of Spiral Wound Reverse Osmosis for Four Radioactive Waste Processing Applications

Abstract

A pilot-scale spiral wound reverse osmosis rig was used to treat four significantly different radioactive waste streams, three of which were generated at the Chalk River Laboratories at AECL. These streams included: 1. A chemical/decontamination (CD/DC) waste stream which is routinely treated by the plant-scale membrane system at CRL; 2. Reactor waste which is a dilute radioactive waste stream (containing primarily tritium and organic acids), and is an effluent from the operating reactors at AECL; 3. An ion exchange regenerant waste stream which contains a mixture of stream (1) (CD/DC), blended with secondary waste from ion exchange regeneration; 4. Boric acid simulated waste which is a by-product waste of the PWR reactors. This was the only stream treated that was not generated as a waste liquid at AECL. For the first three streams specified above, reverse osmosis was used to remove chemical and radiochemical impurities from the water with efficiencies usually exceeding 99%. In these three cases the "permeate" or clean water was the product of the process. In the case of stream (4), reverse osmosis was used in a recovery application for the purpose of recycling boric acid back to the reactor, with the concentrate being the "product ". Reverse osmosis technology was successfully demonstrated for the treatment of all four streams. Prefiltration and oxidation (with photocatalytic continuous oxidation technology) were evaluated as pretreatment alternatives for streams (1), (2), and (3). The results indicated that the effective crossflow velocity through the membrane vessel was more important in determining the extent of membrane fouling than the specific pretreatment strategy employed.